Aluminum atoms possess 13 electrons that aren’t tightly bound by their nuclei and can move around freely – an attribute known as conductivity that makes aluminum an effective electrical insulator.
Alumina offers outstanding electrical insulation alongside other desirable properties such as mechanical rigidity, chemical resilience and high temperature operability. As such, it has long been utilized in aerospace and medical applications as a ceramic crucible material, while it’s used as PCB substrates in manufacturing operations.
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Alumina is one of the most thermally conductive materials on the market, capable of quickly dissipating large amounts of heat quickly to another material or surface, making it suitable for applications requiring rapid heat transfer. Alumina makes an excellent material choice for metal-to-metal contact in high-temperature environments like airplane engines and steam turbines, as well as cooling systems in electronic devices.
Alumina boasts excellent thermal conductivity, efficiently transmitting energy via molecular vibration and collision, rather than through bulk movement of its constituent particles. This feature can be attributed to strong ionic interatomic bonding that gives this material its desirable material properties. Alumina exists in several crystalline phases but most applications involve hexagonal alpha phase which remains stable even at elevated temperatures and which also is among the strongest and stiffest oxide ceramics available, making it suitable for structural applications.
Temperature has an effect on the thermal conductivity of alumina, as its conductivity rises as temperatures do, as its free electrons act as efficient carriers of thermal energy, with higher conductivity for pure metals than alloys. Furthermore, size matters when considering conductivity – larger atoms with greater orbital freedom have greater conductivity than smaller atoms.
Non-metallic crystals also exhibit excellent thermal conductivity, due to phonon movement. Therefore, non-metallics do not experience the same decrease in conductivity when temperatures increase like metallics do – although carrier scattering from defects can lower phonon mobility at temperatures lower than Debye temperature.
Alumina boasts very high thermal conductivity; however, during sintering processes impurities can form that drastically decrease its ability to transfer heat. Contaminants also limit average freedom of phonons in its lattice lattice; hence it is critical that optimal sintering conditions be utilized for your application. At Associated Ceramics our experienced team of engineers can offer advice regarding optimal conditions for producing conductivity ideal for your specific application.
Excellent Resistance to Corrosion
Aluminum’s natural oxide barrier film offers exceptional corrosion protection when exposed to proper surface preparation conditions, blocking oxygen from reaching its underlying aluminum. When this protective film is broken down by destructive forces like air or acidic chemicals, however, corrosion occurs and must be controlled through a dynamic equilibrium between forces which build the compact barrier layer and those which break it down; Alumina resists these destructive forces well; hence its barrier oxide can reform quickly under normal circumstances.
Alumina is insoluble in most acids and alkalines, except hot sulfuric acid and hydrochloric acid solutions, and has the strength to withstand exposure to strong bases like sodium hydroxide. This exceptional chemical stability contributes to its low solubility in these chemicals.
Alumina’s low electrical conductivity and thermal stability make it an excellent material choice for use in applications requiring insulation and substrates, such as ceramic crucibles.
Alumina is well known for its thermal properties as well as its extraordinary hardness (9 on Mohs scale), high strength, wear resistance and corrosion resistance – qualities which enable its use in various life-extending and society-enhancing applications.
Alumina comes in various grain sizes and grades to meet different applications. Most commonly manufactured into powders or grains with sizes from one micron up to 100 microns. Refractories, which feature grades with smaller particle sizes, are typically used in manufacturing furnace linings and kiln liners as well as other high-temperature applications. Industrial and commercial grades with larger particle sizes are known as industrial and commercial alumina and used widely in glass manufacturing, ceramic production and other industrial uses. EWG VERIFIED label indicates that products made with this ingredient may use it, subject to use restrictions and warnings based on company-provided data. Please visit EWG VERIFIED database for more details about ingredients in this product.
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Alumina not only boasts excellent thermal conductivity, but it also exhibits excellent mechanical properties and resistance to corrosion and wear due to its 95% aluminium oxide content – giving it an extremely hard and strong structure – as well as great permeability to visible light and infrared rays, making it suitable for applications such as sealing rings, medical prostheses, laser tube feedthroughs, thermocouple tubes, electronic substrates and ballistic armor.
Aluminum’s raw form offers low resistance to electric current, due to its tightly packed atoms that contain 13 electrons each. However, when treated, added with impurities or formed into alloys resistance increases drastically due to free electrons in their outer shell that don’t belong tightly within their core and can move around freely.
Free electrons interacting with vibrating atoms known as phonons have more chances to collide and disperse, creating resistance. That is why copper has higher electrical conductivity than aluminum.
However, it is possible to enhance the conductivity of alumina through various treatments and processing techniques such as powder refining, the addition of impurities and precipitation strengthening. Impurities help to decrease crystal lattice defects which cause resistivity. And precipitates disperse free electrons to improve conductivity.
Through these processes, it is possible to produce alumina with higher thermal conductivity than raw material. This is done by deep processing the powder via multiple steps of calcining, cleaning and screening that result in more consistent particle sizes and reduced specific surface areas – factors which influence how efficiently alumina absorbs and dissipates heat.
Sintering is another effective method for increasing alumina’s conductivity, offering layer-by-layer printing process densification with controlled compressive residual stresses to increase strength. Sintering curves can be tailored specifically to each application for greater mechanical reliability and better mechanical reliability than monolithic alumina solutions.
Excellent Dielectric Properties
Aluminum is an excellent conductor of electric current when present as its raw form; however, when mixed with other materials it becomes an exceptional dielectric material with superior dielectric properties than copper itself. Alumina (Al2O3) composites have shown to surpass copper when it comes to dielectric properties; with its lower dielectric constant than many industrial ceramics it makes it perfect for electrical insulation or environments where microwave frequencies must pass freely without interference.
Alumina achieves its excellent dielectric properties due to its structure: aluminum’s atoms are tightly held together at their centers, with only a few electrons on their outer shells anchored directly into their orbitals by metal’s core; as these electrons have no anchor point in this way they can move freely when an electric current changes its potential; these conduction electrons make up its electrical conductivity properties.
Once the electrons separate from their aluminum atom, they become positively charged aluminum ions. Alumina boasts such high conductivity that the majority of these conduction electrons can move easily between adjacent aluminum ions – this characteristic makes alumina such an effective conductor.
These properties make alumina an excellent material choice for applications requiring high conductivity at elevated temperatures, coupled with its impressive strength and corrosion resistance, such as in kilns or furnaces.
Alumina’s dielectric properties make it an excellent choice for high-performance ceramic components like spark plugs, which operate under extremely high-temperature environments and must withstand thermal shock without losing structural integrity or proper heat distribution.
Spherical alumina powders are often utilized in the creation of thermally conductive pastes and potting materials, used between electronic devices and their heat sinks to help conduct and dissipate heat efficiently. This high-performance material is widely utilized across numerous industries such as electronics and automotive applications.