Due to its low vapor pressure and solubility in many chemicals, alumina is widely utilized in electrical applications. Furthermore, its superior corrosion-resistance makes it an invaluable material.
Aluminum conducts electricity quite readily when in its raw state; however, surface treatments such as coating and anodizing can decrease conductivity, while paints or other finishes can have similar effects.
导热性
Alumina is an inert ceramic material often used in high-temperature applications such as crucibles and tubes. Alumina features excellent thermal conductivity, meaning heat transfers quickly and efficiently between components, while it has excellent chemical stability for corrosion-resistance in different environments. Thermal conductivity may differ between grades depending on composition or treatment processes employed during production; grades typically have lower thermal conductivities due to this factor.
Metal aluminum has an extensive array of industrial uses, spanning transportation (airplanes, automobiles and boats), building construction (windows or doors) and electricity transmission (cables). Aluminum is also popularly used as food packaging material and household utensil lining material due to its soft, nonmagnetic, ductile properties as well as being corrosion-resistant; all qualities which add tremendous value in many industrial settings.
Metals tend to be great conductors because their electron orbitals are filled with shared electrons. Alumina compounds differ by having orbitals that do not fill fully with shared electrons – meaning their orbitals remain more tightly bound within their atomic structures, leading to much lower thermal conductivity compared to copper but higher thermal conductivity than most ceramics and gallium compounds.
Alumina can be made more thermally conductive through the addition of certain alloying elements and proper annealing procedures, such as Cr, V, Mn and Ti trace alloying elements with their strongest weakening effects.
Silica is the primary alloying agent found in alumina ceramics, increasing their thermal conductivity by an order of magnitude while simultaneously improving abrasion resistance and strength.
Other refractory ceramics, like silicon carbide and boron nitride, possess lower thermal conductivities than alumina; however, its superior refractoriness, corrosion resistance, cost effectiveness, and better thermal conductivity than most metals make alumina an excellent material choice for industrial applications.
Electrical Conductivity
Aluminium oxide’s crystalline structure makes it an effective electrical insulator. The wide gap between its valence and conduction bands requires considerable energy to excite electrons and allow them to flow across it and conduct electricity, and also the layer of Al2O3 formed on top of Alumina prevents electrons from directly touching metal surfaces.
However, some secondary inclusions may form within an alumina matrix and help increase conductivity if percolation thresholds are met; this depends on factors like distribution and aspect ratio of inclusions as well as sintering temperature.
Though low in electrical conductivity, alumina has many applications in electronics and electric power. Its robust dielectric strength enables reliable insulation between conductors such as capacitor components. Furthermore, its exceptional thermal resistance and chemical stability further add to its usefulness.
Alumina ceramics are often employed in manufacturing tiles used in coal-fired power stations to protect areas with high wear from corrosion. Alumina ceramics can also be found widely used as grinding media for cutting or milling various materials ranging from wood to welded metal.
Engineered ceramics that use alumina as their base are another application of its use, specifically tailored for demanding and specialist environments that demand increased wear resistance or other properties. Engineered alumina comes in many varieties depending on its concentration of Al2O3 as well as other additives like titanate, zirconia, silica, chromium corundum or titanium corundum.
Associated Ceramics is an experienced provider of engineered alumina products, and we can work with you to craft exactly the product your application requires. Get in touch with us now to discover more of our capabilities or request a quote for alumina ceramics! Our selection includes sinterable alumina, preforms, abrasive grains and ingots which all undergo stringent quality controls to meet our customers’ specifications.
Chemical Conductivity
Aluminum oxide (or more commonly alumina) is one of the most frequently encountered engineering ceramics today, being one of the most stable and versatile engineering ceramic materials on the market. It boasts excellent wear, thermal and chemical properties as well as strong corrosion and erosion resistance properties. Furthermore, its chemical composition prevents any ions passing through it which acts as a strong electrical insulator; however it can be made conductive through adding graphene reinforcement which can increase conductivity up to 100 million times more than before.
Alumina’s ionic conductivity is determined mainly by its atomic structure and how electrons are distributed among its atoms. An atom contains 13 electrons arranged so they can move freely around within its outer shell allowing electricity to pass freely between electrodes as its outer electrons move to various orbitals or are attracted by potential differences between electrodes.
Alumina’s chemical conductivity depends on both temperature and its physical state. As temperature increases, more easily moving atoms close together can decrease resistance to electrical current flow reducing resistance resistance for electrical current passing through it reducing resistance resistance which causes resistance resistance which makes alumina an electrical insulator when cold but becomes an electrical conductor when warm.
Alumina’s resistance to corrosion makes it an invaluable component in many petrochemical applications. Autothermal reforming reactors (ATR) often use it, producing synthetic gas from hydrocarbons through partial oxidation and catalytic reformation. Alumina’s low solubility in hydrochloric acid and hot sulfuric acid makes it the perfect material for these demanding conditions, which require materials that can withstand both oxidizing and reducing atmospheres.
Additions such as zirconia or silicon dioxide may help alumina’s chemical inertness further by increasing strength, hardness, abrasion resistance and strength; these additions may also increase strength, hardness and abrasion resistance of the material while potentially decreasing conductivity by restricting free electrons in its surface layer reducing electricity transfer capabilities of the refractory material.
Mechanical Conductivity
Alumina is a durable ceramic with exceptional thermal, chemical, and electrical properties. These features make it a highly desirable material for high-temperature applications like crucibles and ceramic tubes; its superior strength, hardness, abrasion resistance, thermal conductivity make it the ideal material for demanding applications that demand both durability and efficiency.
As such, alumina finds numerous applications across several fields, such as metallurgy, energy production, manufacturing and aerospace. Common uses for alumina include use in kilns and furnaces to withstand extreme temperatures while its high heat tolerance enables its use in chemical applications as well.
Although alumina is generally an electrical insulator, when heated it becomes an ionic conductor due to aluminium’s reducing nature and consequent spontaneous oxidisation in air. However, bulk aluminum is coated by a very thin layer of alumina oxide which prevents it from further oxidisation and maintains conductivity.
Alumina oxide is responsible for its resistance to corrosion; it’s highly durable and can endure exposure to acidic chemicals without suffering damage. Furthermore, alumina has an exceptionally high melting point so it can withstand hot environments without cracking under pressure.
Alumina boasts excellent thermal and electrical conductivity as well as mechanical insulation properties, making it an excellent material for mechanical isolation applications. Due to its hardness and abrasion resistance, alumina makes an excellent material for CNC machining applications; however due to its low electrical conductivity, complex-shaped components cannot be produced through electro-discharge machining techniques.
Researchers have taken steps to overcome this hurdle by adding multi-walled carbon nanotubes (MWCNTs) into alumina composites to increase electrical conductivity. In their study, the authors investigated how different concentrations of Multiwall Carbon Nanotubes (MWCNTs) affect electrical conductivity of alumina-based ceramics. MWCNTs were added using colloidal processing, freeze drying and hot pressing processes. For this experiment, two distinct alumina powders were utilized: TMDAR from Taimei Chemicals of Japan and CT 3000 SG from Almatis GmbH of Germany. The composites made with these alumina-based materials were evaluated based on their microstructure and physical properties. Results show that when MWCNTs are added to alumina matrix, electrical conductivity significantly improves. Furthermore, results reveal that debinding temperature and MWCNT concentration both play major roles in increasing electrical conductivity.